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A chiral triaminosulfonium salt: design and application to catalytic asymmetric synthesis

✍ Scribed by Yoshichika Kuroki; Katsuhiko Iseki

Book ID
104262502
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
280 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

The first chiral triaminosulfonium salt, tris((S,S)-3,4-diphenylpyrrolidino)sulfonium difluorotriphenylstannate, catalyzes trifluoromethylation of benzaldehyde with (trifluoromethyl)trimethylsilane to give the corresponding optically active alcohol with 52% ee.

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