𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A Chiral Acrylate Equivalent for Metal-Free Diels−Alder Reactions: endo -2-Acryloylisoborneol

✍ Scribed by Palomo, Claudio; Oiarbide, Mikel; García, Jesús M.; González, Alberto; Lecumberri, Ainara; Linden, Anthony


Book ID
126429002
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
65 KB
Volume
124
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


4-Acetoxycyclopent-2-enone: a synthetic
✍ P.P.M.A. Dols; L. Lacroix; A.J.H. Klunder; B. Zwanenburg 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 319 KB

The Lewis acid catalyzed Diels-Alder reactions of 4-acetoxycyclopentenone 3 with both cyclic and acyclic dienes is described. Subsequent base induced elimination of the B-acetoxy group from the respective cycloadducts Ieaak to bi-and tricyclic erwnes in good yields. The x-facial diastereoselectivity