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A Chiral Acrylate Equivalent for Metal-Free Diels—Alder Reactions: endo-2-Acryloylisoborneol.

✍ Scribed by Claudio Palomo; Mikel Oiarbide; Jesus M. Garcia; Alberto Gonzalez; Ainara Lecumberri; Anthony Linden


Book ID
101931800
Publisher
John Wiley and Sons
Year
2003
Weight
161 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


📜 SIMILAR VOLUMES


4-Acetoxycyclopent-2-enone: a synthetic
✍ P.P.M.A. Dols; L. Lacroix; A.J.H. Klunder; B. Zwanenburg 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 319 KB

The Lewis acid catalyzed Diels-Alder reactions of 4-acetoxycyclopentenone 3 with both cyclic and acyclic dienes is described. Subsequent base induced elimination of the B-acetoxy group from the respective cycloadducts Ieaak to bi-and tricyclic erwnes in good yields. The x-facial diastereoselectivity