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A chemoselective method for nitration of steroids containing aromatic ringA

โœ Scribed by V. M. Rzheznikov; L. E. Golubovskaya; S. A. Shevelev; A. Kh. Shakhnes

Book ID
105596288
Publisher
Springer
Year
1999
Tongue
English
Weight
186 KB
Volume
48
Category
Article
ISSN
1573-9171

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A fast and mild method for the nitration
A fast and mild method for the nitration of aromatic rings
โœ Radoslaw R Bak; Andrew J Smallridge ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 50 KB

The use of N 2 O 5 and a Fe(III) catalyst for the nitration of aromatic rings is described. This methodology is compatible with most functional groups and results in near quantitative yields in 4 min. The reaction conditions are non-oxidising: benzaldehyde and benzyl alcohols are readily nitrated wi