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A chemical study of 2-butyne-1,4-diol

✍ Scribed by M. d'Amboise; D. Mathieu; D.L. Piron


Book ID
118995204
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
517 KB
Volume
35
Category
Article
ISSN
0039-9140

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Hydrogenation of 2-butyne-1,4-diol (B 3 D) using 1% Pt/CaCO 3 catalyst was carried out to give 2-butene-1,4-diol (B 2 D) or butane-1,4-diol (B 1 D) selectively or a mixture of two diols eliminating the formation of acetal, aldehyde, and alcohols as side products. In presence of ammonia, nearly compl

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## Abstract Polyesters of butyne‐1,4‐diol (ByD) and aliphatic dicarboxylic acids (ADAs) were prepared in three different ways. Method I is based on the transesterification of ByD with the dimethyl esters of ADAs in bulk. Although catalyst and temperature were varied, only oligomers were obtained, b