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Continuous Hydrogenation of 2-Butyne-1,4-diol to 2-Butene- and Butane-1,4-diols

✍ Scribed by Rode, C. V.; Tayade, P. R.; Nadgeri, J. M.; Jaganathan, R.; Chaudhari, R. V.


Book ID
120571465
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
163 KB
Volume
10
Category
Article
ISSN
1083-6160

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Platinum catalyzed hydrogenation of 2-bu
✍ M.M. Telkar; C.V. Rode; R. Jaganathan; V.H. Rane; R.V. Chaudhari πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 English βš– 285 KB

Hydrogenation of 2-butyne-1,4-diol (B 3 D) using 1% Pt/CaCO 3 catalyst was carried out to give 2-butene-1,4-diol (B 2 D) or butane-1,4-diol (B 1 D) selectively or a mixture of two diols eliminating the formation of acetal, aldehyde, and alcohols as side products. In presence of ammonia, nearly compl