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A catalytic method for ?-glycol cleavage

โœ Scribed by Barton, Derek H. R.; Motherwell, William B.; Stobie, Alan

Book ID
119997350
Publisher
The Royal Society of Chemistry
Year
1981
Tongue
English
Weight
219 KB
Volume
23
Category
Article
ISSN
0022-4936

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โœ Norma K. Dunlap; Wosenu Mergo; James M. Jones; Jesse D. Carrick ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 86 KB

Oxidative cleavage of a series of glycols using NaIO 4 on silica gel in the presence of a series of stabilized ylides provides access to a number of synthetically useful alkenes. The ease and general utility of this reaction is demonstrated here using several carbohydrates and amino acid derived gly