A Catalytic Homo-Nazarov Cyclization Protocol for the Synthesis of Heteroaromatic Ring-Fused Cyclohexenones
โ Scribed by Phun, Lien H.; Patil, Dadasaheb V.; Cavitt, Marchello A.; France, Stefan
- Book ID
- 118164583
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 55 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1523-7060
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
A highly efficient strategy for the iterative synthesis of a trans-fused polytetrahydropyran ring system was developed. The new iterative method involves SmI2-induced reductive intramolecular cyclization of an aldehyde and a [~-alkoxy acrylate as the key step, producing a 2,3-trans-tetrahydropyran r