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A carbon-13 nuclear magnetic resonance spectral investigation of substituted triphenyl phosphates

✍ Scribed by G. W. Buchanan; R. H. Wightman; M. Malaiyandi

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
296 KB
Volume
19
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

^13^C NMR chemical shifts and ^13^C^31^P couplings are reported for triphenyl phosphate and 13 alkyl derivatives. In ortho‐alkylated materials, it is found that the upfield γ shielding effect is only operative when the carbon atom, situated γ to the exocyclic oxygen, bears at least one hydrogen. Conformational changes about the arylO bond can be monitored via the vicinal ^31^pOC^13^C couplings.

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