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A calorimetric study of early hydration of alkali-slag cements

โœ Scribed by Caijun Shi; Robert L. Day


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
969 KB
Volume
25
Category
Article
ISSN
0008-8846

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โœฆ Synopsis


This paper examines the early hydration of alkali-slag cements activated by different sodium compounds, such as NaOH, Na&O,, Na$iO,.SH,O, Na,PO.,, N%HPO, and NaF, at 25 and 50ยฐC. A conduction calorimeter was used to monitor hydration kinetics. It was found that the initial pH of activator solution has an important role in dissolving the slag and in promoting the early formation of some hydration products. However, further hydration of alkali-slag cements is dominated by the reaction of the anion or anion group of activator and the Ca" dissolved from slag rather than the initial pH of the activator solution. Finally, three models were proposed to describe the early hydration of alkali-slag cements based on heat evolution measurements.


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