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A Calometric study of steric effects in the reactions of phosphorus ligands with Ni(COD)2

โœ Scribed by C.A. Tolman; D.W. Reutter; W.C. Seidel


Book ID
108347367
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
288 KB
Volume
117
Category
Article
ISSN
0022-328X

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The gas phase reaction of chloride ion with alkyl chlorides (methyl, ethyl, propyl, i-propyl,/-butyl, t-butyl and neo-pentyl ) has been studied by ab initio methods. Geometries of stationary points along the reaction coordinate have been optimized at the MP2/6-31 G\* level of theory and improved ene