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Separation of Steric and Electronic Effects in the Reaction Enthalpies of Association of Phosphorus Ligands

✍ Scribed by Dr. Hartmut Schenkluhn; Ing. (grad.) Walter Scheidt; Dr. Bruno Weimann; Ing. (grad.) Manfred Zähres


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
252 KB
Volume
18
Category
Article
ISSN
0044-8249

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Separation of polar and enthalpy effects
✍ Károly Héberger; Antal Lopata; J. Cs. Jászberényi 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 87 KB 👁 2 views

Rate constants (k) of radical addition reactions between 15 carbon-and sulfur-centered radicals and 15 vinyl-type alkenes were collected from the literature. Three descriptor variables {a polar (Hammett) sigma scale [s(H)] and two radical sigma scales as defined by Creary and co-workers [s Á (C)] an