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A bisphenylnitrene complex of molybdenum with a bent nitrene ligand. Preparation and structure of cis-bis(phenylnitrene)bis(diethyldithiocarbamato)molybdenum

✍ Scribed by Haymore, Barry L.; Maatta, Eric A.; Wentworth, R. A. D.


Book ID
126901508
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
767 KB
Volume
101
Category
Article
ISSN
0002-7863

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## Abstract The first Chatt‐type Mo^0^ dinitrogen complex with a tetraphosphane ligand has been prepared and characterized by NMR as well as infrared and Raman spectroscopy. Importantly, the employed reaction route allows the stereospecific synthesis of this complex as __trans__‐[Mo(N~2~)~2~(__meso