✦ LIBER ✦

A biomimetic total synthesis of allomicrophyllone: protective Diels–Alder reaction as a stratagem

✍ Scribed by Goverdhan Mehta; Tabrez Babu Khan

Publisher: Elsevier Science
Year: 2010
Tongue: French
Weight: 493 KB
Volume: 51
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.10.063

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✦ Synopsis

A biomimetic total synthesis of bioactive tetracyclic natural product allomicrophyllone has been achieved in which a protective Diels-Alder reaction employing a disposable sacrificial 1,3-diene directs the regioselectivity of the subsequent Diels-Alder reaction.

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