A Bimetallic Complex Between Uranyl and p-tert-Butylcalix[8]arene
✍ Scribed by Thuéry, P. ;Keller, N. ;Lance, M. ;Vigner, J. D. ;Nierlich, M.
- Book ID
- 114511886
- Publisher
- International Union of Crystallography
- Year
- 1995
- Tongue
- English
- Weight
- 522 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0108-2701
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## Abstract __p__-__tert__-Butyl-calix[8]arene crystallizes with six molecules of __N__-methyl-morpholine in a triclinic lattice, space group __P__1 with __a__ = 12.142(3) Å, __b__ = 16.596(4) Å, __c__ = 17.211(2) Å, __α__ = 83.72(2)°, __β__ = 80.66(2)°, __γ__ = 69.55(2)°, __Z__ = 1. The formation
Differential scanning calorimetry has revealed the presence of an endothermal process at 150.0 " 0.5 K in the w x Ž . p-tert-butylcalix 8 arene 1:1 C , that is not associated with a structural change or a discontinuity. We attributed this event 60 to a new orientational transition which is different