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A Base-Catalyzed Domino-Isomerization–Hydroamination Reaction—A New Synthetic Route to Amphetamines

✍ Scribed by Christian G. Hartung; Claudia Breindl; Annegret Tillack; Matthias Beller

Book ID
104202795
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
109 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis

AbstractÐAn ef®cient synthesis of pharmaceutically interesting amphetamines by a base-catalyzed domino-isomerization±hydroamination reaction is presented. Starting from allylbenzene and various primary or secondary amines, the basic structural pattern of amphetamines is synthesized directly in yields of up to 91% in the presence of catalytic amounts of n-butyllithium.

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