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A 2H n.m.r. study of the steroidal dienone?phenol rearrangement

✍ Scribed by Avent, Antony G.; Hanson, James R.; Yang-Zhi, Ling; Sadler, Ian H.


Book ID
111658763
Publisher
Royal Society of Chemistry
Year
1985
Weight
443 KB
Volume
0
Category
Article
ISSN
1472-7781

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Spiran isolation in the dienone-phenol r
✍ Antoni Planas; Jaime TomΓ‘s; Juan-Julio Bonet πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 219 KB

The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.