A 1:1 cocrystal of 2,7-dicyano-9-dicyanomethylene-4,5-dinitrofluorene and benzonitrile
✍ Scribed by Batsanov, Andrei S. ;Perepichka, Dmitrii F.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 222 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title complex contains in®nite stacks of alternating C 18 H 4 N 6 O 4 and C 7 H 5 N molecules; the former is warped to a much larger extent than in its charge-transfer complex with tetrathiafulvalene.
📜 SIMILAR VOLUMES
Reaction of the electron acceptor 2,5,7-trinitro-4-bromo-9-dicyanomethylene¯uorene (1) and the electron donor 2,6dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylidene)-9,10dihydroanthracene (2) in dioxane resulted in the formation of a novel type of salt with the previously unknown 2,5,7-trinitro-4
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê Disorder in solvent or counterion R factor = 0.047 wR factor = 0.137 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.