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An unexpected TTFAQ donor–fluorene acceptor reaction resulting in a novel salt: 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylium)-anthracene bis(2,5,7-trinitro-4-bromo-9-cyanofluorenide) dioxane trisolvate

✍ Scribed by Batsanov, Andrei S. ;Bryce, Martin R. ;Lyubchik, Svetlana B. ;Perepichka, Igor F.

Publisher: International Union of Crystallography
Year: 2002
Tongue: English
Weight: 503 KB
Volume: 58
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536802016239

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✦ Synopsis

Reaction of the electron acceptor 2,5,7-trinitro-4-bromo-9-dicyanomethylene¯uorene (1) and the electron donor 2,6dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylidene)-9,10dihydroanthracene (2) in dioxane resulted in the formation of a novel type of salt with the previously unknown 2,5,7-trinitro-4-bromo-9-cyano¯uorenide anion (3 À ): (2) 2+ Á(3 À ) 2 Á3C 4 H 8 O 2 .

An unexpected TTFAQ donor–fluorene acceptor reaction resulting in a novel salt: 2,6-di­hexyl­oxy-9,10-bis(4,5-di­methyl-1,3-di­thiol-2-yl­ium)-anthracene bis(2,5,7-tri­nitro-4-bromo-9-cyano­fluorenide) dioxane trisolvate

✦ Synopsis

An unexpected TTFAQ donor–fluorene acceptor reaction resulting in a novel salt: 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylium)-anthracene bis(2,5,7-trinitro-4-bromo-9-cyanofluorenide) dioxane trisolvate