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963. Anhydrides of organophosphorus acids. Part II. The synthesis of tri- and tetra-alkyl esters of phosphorous phosphoric anhydride

โœ Scribed by Michalski, J. ;Modro, T. ;Zwierzak, A.


Book ID
120319037
Publisher
The Royal Society of Chemistry
Year
1961
Weight
295 KB
Category
Article
ISSN
0368-1769

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The generation of alkyl-substituted monomeric metaphosphoric acid esters (ROPO,) 4 in solution is described, utilizing two different methods based o n the condensation of alkyl phosphorodichloridates either with anhydrous potassium hydrogen carbonate or with the novel disodium pyrocarbonate salt 5 ,