ChemInform Abstract: Generation and Trapping of Monomeric Metaphosphoric Acid Esters (cf. ( II)) in Solution: Mechanistic Investigation into the Fragmentation of Mixed Carbonic-Phosphoric Acid Anhydrides and the Chelotropic Breakdown of Cyclic Pyrocarbonate Esters.

Generation and trapping of monomeric met

Generation and trapping of monomeric metaphosphoric acid esters in solution: Mechanistic investigation into the fragmentation of mixed carbonic-phosphoric acid anhydrides and the chelotropic breakdown of cyclic pyrocarbonate esters

✍ Malcolm R. Banks; Ian Gosney; Derek Kilgour; J. I. G. Cadogan; Philip K. G. Hodg 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 994 KB

The generation of alkyl-substituted monomeric metaphosphoric acid esters (ROPO,) 4 in solution is described, utilizing two different methods based o n the condensation of alkyl phosphorodichloridates either with anhydrous potassium hydrogen carbonate or with the novel disodium pyrocarbonate salt 5 ,