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947. Tetrahedral nickel(II) complexes and the factors determining their formation. Part III. Complexes with triarylphosphines

✍ Scribed by Browning, M. C. ;Davies, R. F. B. ;Morgan, D. J. ;Sutton, L. E. ;Venanzi, L. M.

Book ID: 120058663
Publisher: The Royal Society of Chemistry
Year: 1961
Weight: 644 KB
Category: Article
ISSN: 0368-1769
DOI: 10.1039/JR9610004816

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## Abstract The stopped‐flow technique was used to measure the rates of formation and dissociation of tetrahedral [ML~2~] complexes (M^2+^=Ni^2+^ or Co^2+^) of four bidentate S~2~‐donor ‘dithioimidodiphosphato’ ligands L^−^ (HL=[R^1^R^2^P(S)]NH[P(S)R^3^R^4^], R^1^ to R^4^=alkyl) at 25.0° in MeOH/