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9-(9-Borabicyclo[3.3.1]nonyl)-9-azabicyclo[3.3.1]nonane radical cation: a failure of Bredt's rule kinetic stabilization

✍ Scribed by Nelsen, Stephen F.; Kessel, Carl R.; Brien, David J.; Weinhold, Frank


Book ID
127137808
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
470 KB
Volume
45
Category
Article
ISSN
0022-3263

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Bredt's rule. IVβ€”the structure of an all
✍ G. L. Buchanan πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 128 KB

## Abstract Claims that the condensation product of (βˆ’)‐menthone with benzylideneacetophenone is a bridged bicyclic ketol are shown to be erroneous. The true structure is shown by ^13^C n.m.r. to be 2‐(1β€²,3′‐diphenyl‐3′‐oxopropyl)‐3‐methyl‐6‐isopropylcyclohexanone.