9-(2,3,4-tri-O-benzyl-D-arabinopyranosyl)Purines
✍ Scribed by Martinez, Abelardo P.; Lee, William Wei; Goodman, Leon
- Book ID
- 125968426
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 152 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0022-2623
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The known tendency of halogen or alkoxyl groups on C-l in a pyranose system to adopt an axial conformation is generally designated as the anomeric effect. This effect plays an important and frequently discussed role in the field of conformational analysis of carbohydrates and related acetals '. The
Sugar intermediates 4-C-methyl-2,3,5-tri-O-benzyl-D-ribofuranose (8b) and 4-C-methyl-2,3,5-tri-O-benzyl-L-lyxofuranose (8a) were synthesized by addition of alkylithium reagents to pentanones 3a,b. The nucleophilic additions proceeded with good stereoselectivity and good yields to give the titled com
## Abstract Die Polykondensation der 2,3,6‐Tri‐__O__‐benzyl‐D‐glucose **(1)** und der 2,3,4‐Tri‐__O__‐benzyl‐D‐glucose **(3)** läßt sich unter Protonenkatalyse nicht durchführen, weil beide Verbindungen in ihre inneren Anhydride [1, 4‐Anhydro‐2,3,6‐tri‐__O__‐benzyl‐α‐D‐glucose **(2)** bzw. 1,6‐Anhy