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87Rb NMR investigations on binary and ternary fullerene compounds: Rb3C60, K2RbC60and Rb2CsC60

✍ Scribed by M. Kanowski; H. Werner; R. Schlögl; H. -M. Vieth; K. Lüders


Book ID
113000788
Publisher
Springer Vienna
Year
1996
Tongue
English
Weight
374 KB
Volume
11
Category
Article
ISSN
0937-9347

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Local structures around the Rb+ ion in K
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Rb K-edge EXAFS has been studied for K2RbC6o at 21 and 39 K and for KRb2C6o at 10 and 27 K. It is shown that the Rb + ions in K 2RbC60 occupy the center of the octahedral site, contrary to a previous report based on Rb K-edge EXAFS at room temperature that the Rb + ions are off-centered. It is also