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8 and 16-Membered ring phosphorus compounds. Ring size dependence of the NMR parameters

✍ Scribed by J. Martin; J. B. Robert

Book ID: 102952250
Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 628 KB
Volume: 15
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270150118

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✦ Synopsis

Abstract

The ^1^H NMR spectral analysis of four 8‐membered rings, 2‐thioxo‐ (or 2‐oxo‐) 2‐R‐1,3,6,2‐ trithiaphocane, is reported. The stereochemistry of the 8‐membered ring is discussed. The ^31^P NMR spectral parameters [δ^31^P, ^1^J(PC)] obtained on several cyclic 1,3,2‐dithiaphospha compounds of variable size (5, 6, 8, 12 and 16‐membered rings) are discussed as a function of the ring size and of the geometry of the molecule.

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