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Unsaturated 8-membered ring compounds. VII. Synthesis and cycloaddition reactions of 7,8-dimethylene-1,3,5-cyclooctatrienes. The synthesis of dicyclooctatetraeno[1,2:4,5]benzene

โœ Scribed by Elix, J. A.; Sargent, Melvyn V.; Sondheimer, F.


Book ID
126774818
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
927 KB
Volume
92
Category
Article
ISSN
0002-7863

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Synthesis and a [ฯ€2s+ ฯ€2s+ ฯ€2s] cycloadd
โœ Masaji Oda; Nobuyuki Fukazawa; Yoshio Kitahara ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 238 KB

Dimethylenecyclopolyenes of type 1. are an interesting class of compounds. The n=l member of this class is 3,6-dimethylene-1,4-cyclohexadiene 2 which is an important intermediate for [2.2]paracyclophane. 1 -Of two possible dimethylenecyclooctatrienes, 7,8-dimethylene-1,3,5-cyclooctatriene 2 was sy