8-Amino-6-quinolyl Methyl Sulfone
✍ Scribed by Gilman, Henry; Lindblad, Albin E.
- Book ID
- 126925890
- Publisher
- American Chemical Society
- Year
- 1946
- Tongue
- English
- Weight
- 221 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The title compound, C 26 H 22 N 2 O, was readily synthesized from the reaction between 8-aminoquinoline and 9-anthraldehyde in EtOH solution. There is an intramolecular NÐHÁ Á ÁN hydrogen bond and weak CÐHÁ Á ÁN/O interactions. The molecule self-assembles into a zigzag chain along the c axis through
In the crystal structure of the title compound, C 26 H 34 N 2 O 3 S, the quinoline ring system, with methoxy and methyl substituents, is nearly planar. An intramolecular hydrogen bond [N-HÁ Á ÁN = 2.16 (2) A ˚] is observed.
Single-crystal X-ray study T = 299 K Mean (C-C) = 0.004 A R factor = 0.046 wR factor = 0.131 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Cd(NO 3 ) 2 (C 25 H 19 N 3 O 2 )], the coordination environment around cadmium consists of four O and three N atoms in the form of a distorted pentagonal bipyramid.