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746. A potentiometric study of the reduction by potassium iodide of potassium bromate in sulphuric and hydrochloric acid solutions

✍ Scribed by Britton, H. T. S. ;Britton, H. Greenslade


Book ID
115524633
Publisher
The Royal Society of Chemistry
Year
1952
Weight
530 KB
Category
Article
ISSN
0368-1769

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A kinetic study of the oxidation of Ξ±-hy
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## Abstract The oxidation of α‐hydroxy acids and α‐hydroxy ketones by Br(V) follows the rate‐law However, the former reaction exhibits a second‐order dependence on hydrogen ion concentration while the latter reaction has a third‐order dependence. A mechanism involving a slow formation of a bromate