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7-(Trifluormethyl)-1λ4,3λ4,5λ4,-trithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-1(9),2,3,5,7-pentaen als Komplexligand

✍ Scribed by Maggiulli, Roberto ;Mews, Rüdiger ;Stohrer, Wolf-Dieter ;Noltemeyer, Mathias

Publisher: Wiley (John Wiley & Sons)
Year: 1990
Tongue: English
Weight: 592 KB
Volume: 123
Category: Article
ISSN: 0009-2940
DOI: 10.1002/cber.19901230107

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The title compound S4) reacts with secondary amines HNR, (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 1 : 1 to give 9 and 10, with primary amines HzNR (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 2 : 2 by rearrangement ofan F-atom to form 11 and 12. The P-fluorinated compound 13 is obtained