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(6R,10R,14E)-6-Amino-12-ethyl­idene-8-methyl-6,7,10,12-tetra­hydro-6,10-methano­cyclo­octa­[b]pyridin-2(1H)-one monohydrate

✍ Scribed by Meng, Zhao-Ling ;Sun, Ai-Ling ;Liu, Ren-Min ;Wang, Da-Qi

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
210 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The crystal structure of the title compound, C 15 H 18 N 2 OÁH 2 O, exhibits four independent hydrogen bonds, of types N-HÁ Á ÁO and O-HÁ Á ÁO. The water molecules participate in extensive hydrogen bonding and link molecules into a twodimensional network.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.045 wR factor = 0.124 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The molecule of the title compoumd, C 37 H 52 N 2 O 3 , exhibits a propeller-like conformation, influenced by one intramolecular C-HÁ Á ÁN and four intramolecular C-HÁ Á ÁO hydrogen bonds. In the crystal structure, there are four weak C-HÁ Á Á interactions.