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68. Halogenated ketones. Part III. The preparation of bromomethyl ketones by the diazomethane reaction

โœ Scribed by Catch, J. R. ;Elliott, D. F. ;Hey, D. H. ;Jones, E. R. H.


Book ID
121453981
Publisher
The Royal Society of Chemistry
Year
1948
Weight
115 KB
Category
Article
ISSN
0368-1769

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The reaction of trialkylstannylmethyllit
โœ Tadashi Sato; Toshihiro Kikuchi; Norio Sootome; Eigoro Murayama ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 224 KB

a,@-Epoxy ketones 2\_, upon treatment with two equivalents of trialkylstannylmethyllithium 1, afforded cyclopropanols 2 as a single product in acyclic system, and a mixture of cyclopropanols 2 and methylene 1,2-diols 2 in cyclic system. Under acidic conditions, the cyclopropanols gave p,y-unsaturate