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61 Helices from Tetrahedral Ribbons [BP2O]: Isostructural Borophosphates MIMII(H2O)2[BP2O8] · H2O (MI = Na, K; MII = Mg, Mn, Fe, Co, Ni, Zn) and Their Dehydration to Microporous Phases MIMII(H2O)[BP2O8]

✍ Scribed by Prof. Dr. Rüdiger Kniep; Dipl.-Ing. Horst Günter Will; Dipl.-Ing. Insan Boy; Dr. Caroline Röhr

Book ID: 102728003
Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 946 KB
Volume: 36
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199710131

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Crystals of NaZn(H2O)2[BP2O8].H2O were grown under mild hydrothermal conditions at 170 degrees C. The crystal structure (solved by X-ray single-crystal methods: hexagonal, P6(1)22 (no. 178), a = 946.2(2), c= 1583.5(1) pm, V= 1227.8(4).10(6) pm3, Z = 6) exhibits a chiral octahedral-tetrahedral framew

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