6-OXA-3-phosphabicyclo[3.1.0]hexane 3-oxide derivatives
✍ Scribed by B. A. Arbuzov; A. P. Rakov; A. O. Vizel; L. A. Shapshinskaya; N. P. Kulikova
- Book ID
- 112481440
- Publisher
- Springer
- Year
- 1968
- Tongue
- English
- Weight
- 486 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1573-9171
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Preparation of P-am ino-3-phosphabicy clo [ 3.1.01hexane 3-oxides either by addition of dichlorocarbene to the double bond of l-amino-2,5-dihydro-l Hphosphole 1 -oxides or by substitution of the P-chloro derivative of the bicyclic system was accomplished. Two different diastereomers are obtained by
Several 3-phosphabicyclo[3.1 .O] hexane 3-oxides have been transformed into the corresponding sulfides by reaction with phosphoms pentasulfide. The 3-phenyl derivative could also be prepared by deoxygenation of the oxide followed by reaction with elemental sulfur. Opening of the cyclopropane ring in