6-Methoxy-5-(phenyldiazenyl)salicylaldehyde
✍ Scribed by Ersanlı, Cem Cüneyt ;Odabaşoğlu, Mustafa ;Albayrak, Çigˇdem ;Erdönmez, Ahmet
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 161 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.042 wR factor = 0.100 Data-to-parameter ratio = 14.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The molecules of the title compound, C 16 H 16 N 2 O 4 , are linked by hydrogen bonds into a zigzag chain running along the c axis of the monoclinic cell.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.051 wR factor = 0.131 Data-to-parameter ratio = 12.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 291 K Mean '(C±C) = 0.003 A Ê R factor = 0.043 wR factor = 0.116 Data-to-parameter ratio = 11.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 19 H 23 N 3 O 5 , adopts the keto±amine tautomeric form and the con®guration around the ÐN NÐ double bond is trans. There is an intramolecular NÐHÁ Á ÁO hydrogen bond and intermolecular OÐHÁ Á ÁO interactions, forming a three-dimensional network.
Eine wal3rige A u f s c h l b u n g des Triazols wird mit iiberschiissigem Bromwasser versetzt, wobei es sich tief dunkelbraun farbt, dann wird das iiberschiissige Brom durch Kochen entfernt, wobei das Reaktionsprodukt wieder fast weiB wird. Aus Alkohol Schmp. 1680. 0.0815 g Sbst.: 13.8 ccm N (16O,