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6-Hydr­oxy-1-(4-hydroxy­benz­yl)-7-meth­oxy-2,2-dimethyl-1,2,3,4-tetra­hydro­isoquinolinium thio­cyanate

✍ Scribed by Yang, Jian ;Zhao, Wei

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
236 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The N-containing ring of the tetrahydroisoquinolinium ion of the title compound, C~19~H~24~NO~3~
^+^·SCN^−^, has a half-chair conformation. There is a network of hydrogen bonds between the phenolic groups and thiocyanate anions.

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The asymmetric unit of the title compound, C 17 H 19 NO 2 S, contains two independent molecules with different conformations. Both molecules are linked by intermolecular N-HÁ Á ÁO hydrogen bonds [NÁ Á ÁO = 3.033 (4) and 2.969 (4) A ˚] to form two types of one-dimensional chains running in the b dire

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