In the title compound, C 22 H 24 ClNO 5 , the carbonyl group is in an s-cis configuration with respect to the olefinic double bond. In the crystal structure, there are weak -stacking interactions but there are no significant intermolecular hydrogen bonds.
2-(2-Chloroacetyl)-6,7-dimethoxy-1-(phenoxymethyl)-1,2,3,4-tetrahydroisoquinoline
✍ Scribed by Zou, Zhi-Hong ;Ling, Yong ;Huang, Wen-Long
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 136 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The molecule of the title compound, C 22 H 22 O 2 , possesses a crystallographically imposed twofold axis. The two terminal phenyl rings both make a dihedral angle of 82.5 (2) with the central benzene ring. The crystal packing is stabilized mainly by van der Waals forces.
In the title compound, C 16 H 13 Cl 3 N 6 O 3 S, the substituted triazole ring is bound via a methylene bridge to a chlorothiazole unit. There is evidence for significant electron delocalization in the triazolyl system. Both intra-and intermolecular hydrogen bonds are found in the structure.