## Synthesis a b s t r a c t A series of mono-substituted and bis-substituted derivatives of thieno [3,4-d]-1,3-dithiol-2-one were prepared through halogenation, chloromethylation, and subsequent nucleophilic substitution reactions. Compounds were characterized by NMR, FT-IR, and HRMS.
5,6-Dihydrothieno[2,3-d][1,3]dithiol-2-one
✍ Scribed by Santos, Isabel C. ;Belo, Dulce ;Mendonça, Joana ;Figueira, Mauro João ;Almeida, Manuel ;Rovira, Concepcion
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 130 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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## Synthesis of 7,12-Dihydro-indo~o[3~[l]benzazepin-6-(~~nes and gll-Dihydr~.thieno-[3'3':~]~zepino[qS-b]indol-5(4H)-one The title compounds 4 and 6 were prepared by Fischer indole synthesis. 4a is substituted in 10-position by reaction with bromine in glacial acetic acid. A fast ring inversion is