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5,6-dihydro-α-pyrones and two bicyclic tetrahydro-α-pyrone derivatives from Cryptocarya latifolia

✍ Scribed by Siegfried E. Drewes; Bethuel M. Sehlapelo; Marion M. Horn; Robert Scott-Shaw; Peter Sandor


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
275 KB
Volume
38
Category
Article
ISSN
0031-9422

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Starting from (S)-malic acid and (S)-glycidol, the first total synthesis of strictifolione, a new 6-(v-phenylalkenyl)-5,6dihydro-a-pyrone isolated from Cryptocarya strictifolia, was accomplished, which confirmed its structure including the absolute configuration of the asymmetric centers.