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524. Allylic bromination of unsaturated terpene hydrocarbons, and the synthesis of αβ-unsaturated alcohols

✍ Scribed by Macbeth, A. Killen ;Milligan, B. ;Shannon, J. S.

Book ID
111694586
Publisher
The Royal Society of Chemistry
Year
1953
Weight
305 KB
Volume
0
Category
Article
ISSN
0368-1769

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Contribution to the bromination of conju
Contribution to the bromination of conjugate unsaturated ketones: Synthesis of α,β-unsaturated bromo ketones
✍ V. Calo'; L. Lopez; G. Pesce; P.E. Todesco 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 317 KB

Selective bromination of a&unsaturated ketones has been achieved by the action of 2,4,4,6tetrabromocyclohexa-2$dienone. The stereochemistry, conformation and relative stability of the bromination products of some steroidic unsaturated ketones have been also determined.