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5-Methyl-5bβ,6,7,8,9,11aα-hexa­hydro-5H-indolizino[1,2-b]indol-11(5aαH)-one

✍ Scribed by Badenock, Jeanese C. ;Fraser, Heidi L. ;Gribble, Gordon W. ;Jasinski, Jerry P.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
116 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 5 H 18 N 2 O, reveals a cis-trans stereochemistry for this rare example of the 5H-indolizino[1,2b]indole ring system.

📜 SIMILAR VOLUMES

10-Methyl-8,9,10,11,11a,12-hexa­hydro-5H
10-Methyl-8,9,10,11,11a,12-hexa­hydro-5H,7H-iso­quinolino[3,2-g][1,3,5]triazepine-7,11-dione
✍ Lena, Gersande ;Wenger, Emmanuel ;Guichard, Gilles ;Didierjean, Claude 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 245 KB

In the title compound, C 13 H 15 N 3 O 2 , the triazepane ring adopts a twist-boat conformation and the piperidine ring adopts a boat conformation. The molecular packing is stabilized by N-HÁ Á ÁO, C-HÁ Á ÁO, C-HÁ Á Á and van der Waals interactions.

(1α,6α,7α,7aβ)-2,3,5,6,7,7a-Hexa­hydro-1
(1α,6α,7α,7aβ)-2,3,5,6,7,7a-Hexa­hydro-1,6-epoxy-1H-pyrrolizin-7-ol
✍ Glass, Richard S. ;Deardorff, Donald R. ;Stessman, Nhu Y. T. ;Carducci, Michael 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 163 KB

Single-crystal X-ray study T = 200 K Mean '(C±C) = 0.003 A Ê R factor = 0.032 wR factor = 0.081 Data-to-parameter ratio = 9.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.