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5-Formyl- and 10-formyl-5,6,7,8-tetrahydrofolate. Conformation of the tetrahydropyrazine ring and formyl group in solution

✍ Scribed by Poe, Martin; Benkovic, Stephen J.

Book ID: 126491103
Publisher: American Chemical Society
Year: 1980
Tongue: English
Weight: 860 KB
Volume: 19
Category: Article
ISSN: 0006-2960
DOI: 10.1021/bi00561a006

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## Abstract [^3^H] 5,10‐dideaza‐5,6,7,8‐tetrahydrofolate, DDATHF, was obtained by a two step process. First, 2n[^3^H~2~O] was produced in the reaction flask containing m[^1^HAc] by the reduction of n[PtO~2~] with ^3^H~2~, so that a 1[^3^H^+^]:18[^3^H^+^ + ^1^H^+^] ratio of solvent protic species in