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5-Chloro-2-methyl-3-methyl­sulfinyl-1-benzofuran

✍ Scribed by Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
178 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 10 H 9 ClO 2 S, was prepared by the oxidation of 5-chloro-2-methyl-3-methylsulfanyl-1-benzofuran using 3-chloroperbenzoic acid. The benzofuran ring system is almost planar. Noor -CH 2 -HÁ Á Á interactions were observed.

📜 SIMILAR VOLUMES

5-Chloro-3-methyl­sulfinyl-2-phenyl-1-be
5-Chloro-3-methyl­sulfinyl-2-phenyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 179 KB

The title compound, C~15~H~11~ClO~2~S, was prepared by the oxidation of 5-chloro-3-methylsulfanyl-2-phenyl-1-benzofuran using 3-chloroperbenzoic acid. The 1-benzofuran ring system is almost planar. The crystal structure is stabilized by weak aromatic π–π stacking and –CH~2~—H...π interactions.

2-Methyl-3-methyl­sulfinyl-5-phenyl-1-be
2-Methyl-3-methyl­sulfinyl-5-phenyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Lee, Hee Kyung ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 97 KB

The title compound, C 16 H 14 O 2 S, was prepared by oxidation of 2-methyl-3-methylsulfanyl-5-phenyl-1-benzofuran using 3chloroperbenzoic acid. Shortstacking distances are prevented by the steric influence of the methylsulfinyl group.

2,5-Dimethyl-3-methyl­sulfinyl-1-benzofu
2,5-Dimethyl-3-methyl­sulfinyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 192 KB

The title compound, C 11 H 12 O 2 S, was prepared by the oxidation of 2,5-dimethyl-3-methylsulfanyl-1-benzofuran using 3-chloroperbenzoic acid. The 1-benzofuran ring system is essentially planar. The crystal structure is stabilized by-CH 2 -HÁ Á Á interactions.

5-Methyl-3-methylsulfinyl-2-phenyl-1-ben
5-Methyl-3-methylsulfinyl-2-phenyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 752 KB

The title compound, C 16 H 14 O 2 S, was prepared by the oxidation of 3,5-dimethyl-2-phenyl-1-benzofuran using 3chloroperbenzoic acid. The O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The phenyl ring is rotated out of th

5-Bromo-3-methyl­sulfinyl-2-phenyl-1-ben
5-Bromo-3-methyl­sulfinyl-2-phenyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 181 KB

The title compound, C~15~H~11~BrO~2~S, was prepared by oxidation of 5-bromo-3-methylsulfanyl-2-phenyl-1-benzofuran using 3-chloroperbenzoic acid. The crystal structure is stabilized by aromatic π–π stacking and CH~2~—H...π interactions.