𝔖 Bobbio Scriptorium
✦   LIBER   ✦

2,5-Dimethyl-3-methyl­sulfinyl-1-benzofuran

✍ Scribed by Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
192 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, C 11 H 12 O 2 S, was prepared by the oxidation of 2,5-dimethyl-3-methylsulfanyl-1-benzofuran using 3-chloroperbenzoic acid. The 1-benzofuran ring system is essentially planar. The crystal structure is stabilized by-CH 2 -HÁ Á Á interactions.

📜 SIMILAR VOLUMES

2-Methyl-3-methyl­sulfinyl-5-phenyl-1-be
2-Methyl-3-methyl­sulfinyl-5-phenyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Lee, Hee Kyung ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 97 KB

The title compound, C 16 H 14 O 2 S, was prepared by oxidation of 2-methyl-3-methylsulfanyl-5-phenyl-1-benzofuran using 3chloroperbenzoic acid. Shortstacking distances are prevented by the steric influence of the methylsulfinyl group.

5-Chloro-2-methyl-3-methyl­sulfinyl-1-be
5-Chloro-2-methyl-3-methyl­sulfinyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 178 KB

The title compound, C 10 H 9 ClO 2 S, was prepared by the oxidation of 5-chloro-2-methyl-3-methylsulfanyl-1-benzofuran using 3-chloroperbenzoic acid. The benzofuran ring system is almost planar. Noor -CH 2 -HÁ Á Á interactions were observed.

5-Chloro-3-methyl­sulfinyl-2-phenyl-1-be
5-Chloro-3-methyl­sulfinyl-2-phenyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 179 KB

The title compound, C~15~H~11~ClO~2~S, was prepared by the oxidation of 5-chloro-3-methylsulfanyl-2-phenyl-1-benzofuran using 3-chloroperbenzoic acid. The 1-benzofuran ring system is almost planar. The crystal structure is stabilized by weak aromatic π–π stacking and –CH~2~—H...π interactions.

5-Bromo-3-methyl­sulfinyl-2-phenyl-1-ben
5-Bromo-3-methyl­sulfinyl-2-phenyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 181 KB

The title compound, C~15~H~11~BrO~2~S, was prepared by oxidation of 5-bromo-3-methylsulfanyl-2-phenyl-1-benzofuran using 3-chloroperbenzoic acid. The crystal structure is stabilized by aromatic π–π stacking and CH~2~—H...π interactions.

2-(4-Bromophenyl)-5,7-dimethyl-3-methyls
2-(4-Bromophenyl)-5,7-dimethyl-3-methylsulfinyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 578 KB

The title compound, C~17~H~15~BrO~2~S, was prepared by the oxidation of 2-(4-bromophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran using 3-chloroperbenzoic acid. The 4-bromophenyl ring is rotated out of the benzofuran plane, with a dihedral angle of 19.3 (2)°. The O atom and the methyl group of th

2-Methyl-5,6-methylenedioxy-3-methylsulf
2-Methyl-5,6-methylenedioxy-3-methylsulfinyl-1-benzofuran
✍ Choi, Hong Dae ;Seo, Pil Ja ;Lee, Jong Back ;Son, Byeng Wha ;Lee, Uk 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 178 KB

The title compound, C 11 H 10 O 4 S, was prepared by oxidation of 2-methyl-5,6-methylenedioxy-3-methylsulfanyl-1-benzofuran using 3-chloroperbenzoic acid. The 5,6-methylenedioxybenzofuran ring system is almost planar. The crystal structure contains aromaticstacking and CH 2 -HÁ Á Á interactions.