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5-(4-Methoxy­phenyl)-4-methyl­thia­zole-2(3H)-thione

✍ Scribed by Hartung, Jens ;Daniel, Kristina ;Svoboda, Ingrid ;Fuess, Hartmut

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
138 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The molecules of the title compound, C 11 H 11 NOS 2 , form hydrogen-bonded dimers in the solid state. The amide H atom serves as hydrogen-bond donor and the thiocarbonyl S atom of a neighbouring molecule serves as acceptor. The pmethoxyphenyl substituent is tilted by 7.3 (5) from the thiazole-2(3H)-thione plane.

📜 SIMILAR VOLUMES

5-Acetyl-4-methyl-2-phenyl­amino-1,3-thi
5-Acetyl-4-methyl-2-phenyl­amino-1,3-thia­zole
✍ Kasim, Noor Azilah M. ;Yamin, Bohari M. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 239 KB

The asymmetric unit of the title compound, C 12 H 12 N 2 OS, contains two crystallographically independent molecules. Both molecules are essentially planar and stabilized by intraand intermolecular hydrogen-bonding interactions to form one-dimensional zigzag polymeric chains parallel to the c axis.

3-Cyclo­hexyl-4-(3-methyl-3-phenyl­cyclo
3-Cyclo­hexyl-4-(3-methyl-3-phenyl­cyclo­butyl)-1,3-thia­zole-2(3H)-thione
✍ Kırılmış, Cumhur ;Koca, Murat ;Arıcı, Cengiz ;Heinemann, Frank W. ;Ahmedzade, Mi 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 128 KB

The cyclohexyl ring of the title compound, C 20 H 25 NS 2 , has a chair conformation. The dihedral angle between the thiazole and phenyl rings is 89.70 (2) . The crystal structure involves two weak intramolecular C-HÁ Á ÁS hydrogen-bond contacts.

3-Butyl-4-(3-methyl-3-phenyl­cyclo­but-1
3-Butyl-4-(3-methyl-3-phenyl­cyclo­but-1-yl)-1,3-thia­zole-2(3H)-thione
✍ Kırılmış, Cumhur ;Koca, Murat ;Arıcı, Cengiz ;Heinemann, Frank W. ;Ahmedzade, Mi 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 117 KB

In the title compound, C 18 H 23 NS 2 , the bond lengths and angles are unexceptional. The butyl chain is in a fully extended conformation. The dihedral angle between the thiazole and phenyl rings is 87.21 (2) . The crystal structure is stabilized by one weak intramolecular C-HÁ Á ÁS hydrogen bond.

5-Acetyl-4-methyl-2-(2-fluoro­phenyl­ami
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✍ Kasim, Noor Azilah M. ;Akbari, Aulia ;Yamin, Bohari M. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 188 KB

The molecular structure of (I), with 50% probability displacement ellipsoids.

N-Hydr­oxy-4,5-dimethyl­thia­zole-2(3H)-
N-Hydr­oxy-4,5-dimethyl­thia­zole-2(3H)-thione hemihydrate
✍ Hartung, Jens ;Daniel, Kristina ;Gottwald, Thomas ;Svoboda, Ingrid ;Fuess, Hartm 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 199 KB

The geometry of the title compound, C 5 H 7 NOS 2 Á0.5H 2 O, is characterized by a planar N,S-heterocyclic core that is distorted from a regular pentagon. Solvent water participates in non-chelated hydrogen bonds and acts as a twofold donor (O-HÁ Á ÁS C) and a twofold acceptor [OÁ Á ÁH-O(-N)].

5-Phenyl-1,2,4-triazolo­[3,4-b]­benzo­th
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✍ Abdul Ajees, A. ;Karthikeyan, S. ;Jayanthi, G. ;Ramakrishnan, V. T. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 181 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.045 wR factor = 0.128 Data-to-parameter ratio = 13.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.