5-(3-Hydroxypropyl)-4-(3-phenylallylideneamino)-2,4-dihydro-1,2,4-triazole-3-thione
✍ Scribed by Zou, Kai-Huang ;Zhang, Li-Xue ;Jin, Jian-Yu ;Xiao, Hong-Ping ;Zhang, Jing
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 120 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, C 12 H 11 N 7 OS, the dihedral angles made by the thione-substituted triazole ring with the other triazole ring and the benzene ring are 71.56 (2) and 47.89 (3) , respectively. Inter-and intramolcular hydrogen-bond interactions stabilize the structure.
The acyclic C=N double bond of the title compound, C~10~H~10~N~4~S, is __trans__ configured. The molecule is almost planar. The angle between the two rings is just 10.25 (7)°. The crystal packing is stabilized by N—H...S hydrogen bonds and π–π interactions.
In the title compound, C 16 H 15 N 3 OS, molecules form inversionrelated dimers via N-HÁ Á ÁS hydrogen bonds. The structure is further stabilized by intermolecularstacking interactions down the a axis.
In the title compound, C 15 H 19 N 5 OS, the morpholine ring adopts a chair conformation. The mean plane of the pyridine ring makes a dihedral angle of 35.16 (7) with the triazole ring plane.