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5′-(2-Chloro­phenyl)-1′-methyl-2′',3′′-di­hydro­indoline-3-spiro-3′-pyrrolidine-4′-spiro-2′′-(1,3-benzimidazo­[2,1-b]­thia­zole)-2,3′′-dione dioxane hemisolvate

✍ Scribed by Li, Xiao-Fang ;Feng, Ya-Qing ;Li, Gang ;Wang, Guan


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
162 KB
Volume
59
Category
Article
ISSN
1600-5368

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In the title compound, C 26 H 18 Cl 2 N 4 O 2 S, the two spiro junctions link a planar 2-oxindole ring, a pyrrolidine ring in an envelope conformation and a planar benzo [4,5]imidazo[2,1-b]thiazol-3-one ring. Molecules form dimers connected by NÐHÁ Á ÁN hydrogen bonds.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê Disorder in main residue R factor = 0.047 wR factor = 0.119 Data-to-parameter ratio = 13.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title compound, C 43 H 36 Cl 2 N 4 O 3 Á0.5C 6 H 6 , there exists a trispiro ring system, which consists of a planar 2-oxindole ring, an envelope pyrrolidine ring, an envelope isoxazoline ring and a boat-shaped piperidone ring. The crystal structure is stabilized by NÐHÁ Á ÁN intermolecular i