4,8,9,10-Tetrakis(4-chlorophenyl)-1,3-diazaadamantan-6-one
✍ Scribed by Krishnakumar, R. V. ;Nandhini, M. Subha ;Vijayakumar, V. ;Natarajan, S. ;Sundaravadivelu, M. ;Perumal, S. ;Mostad, A.
- Publisher
- International Union of Crystallography
- Year
- 2001
- Tongue
- English
- Weight
- 380 KB
- Volume
- 57
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 32 H 24 Cl 4 N 2 O, all four six-membered rings which constitute the diazaadamantanone cage adopt chair conformations. The crystal structure is stabilized by ClÁ Á ÁCl interactions and CÐHÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.051 wR factor = 0.147 Data-to-parameter ratio = 10.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 35 H 24 Cl 6 N 2 O 3 , which was synthesized by the [3 + 2]-cycloaddition of 2,6-dichlorobenzonitrile oxide and 2,7-bis(4-chlorobenzylidene)cycloheptanone, contains two independent molecules in the asymmetric unit. Three rings are linked by two spiro-C atoms. The cycloheptanone
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.048 wR factor = 0.135 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.