4,6-O-Benzylidene-Directed β-Mannopyranosylation and α-Glucopyranosylation: The 2-Deoxy-2-fluoro and 3-Deoxy-3-fluoro Series of Donors and the Importance of the O2—C2—C3—O3 Interaction.
✍ Scribed by David Crich; Linfeng Li
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 38 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
Condensation of benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-a-D-galactopyranoside with 2,3,4-tri-o-acetyl-a-D-fucopyranosyl bromide in 1: 1 nitromethane-benzene, in the presence of powdered mercuric cyanide, afforded benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-0-(2,3,4-tri-O-acetyl-P-D-fucopyran
The crystal structure of a-D-Manp-(1 +3)-/?-D-Manp-( 1-+4)-a-D-GlcNAcp has been determined by the direct method using the multi-solution, tangentzformula, and "magic integer" procedures. The space group is P2,, and 2 molecules are in the unit cell with c1 = 9.894 ( 5), b = 10.372 (6), c = 11.816 (6)