4,5,10,11,12,13-Hexahydro-10,13a-methanocycloocta[c]pyrrolo[3,2,1-ij]quinoline-7,9,14-trione and dimethyl 4,5,10,11,12,12a-hexahydroindolo[1,7-cd]benzazepine-7,8-dicarboxylate
β Scribed by Abbott, P. J. ;Acheson, R. M. ;Procter, G. ;Watkin, D. J.
- Book ID
- 114525262
- Publisher
- International Union of Crystallography
- Year
- 1978
- Weight
- 377 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0567-7408
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π SIMILAR VOLUMES
2,7 ]tridecan-13-one reacts with 2-aminobenzyl alcohol to form the title compound, C 26 H 29 NO, which crystallizes with two independent molecules in the asymmetric unit. The N atom shows a nearly planar coordination owing to the strain imposed on the fused-ring compound.
The Mn^V^ complex in the title compound, (C~8~H~20~N)[Mn(C~21~H~26~N~4~O~4~)O], is interesting as it has been suggested that Mn^V^ oxospecies are intermediates both in epoxidation of alkenes and in water oxidation in PSII, __i.e.__ photosystem II, the protein found in oxygenic photosynthetic organis